Broadband and High Sensitive Time-of-Flight Diffraction Ultrasonic Transducers Based on PMNT/Epoxy 1–3 Piezoelectric Composite

5-6 MHz PMNT/epoxy 1-3 composites were prepared by a modified dice-and-fill method. They exhibit excellent properties for ultrasonic transducer applications, such as ultrahigh thickness electromechanical coupling coefficient k(t) (85.7%), large piezoelectric coefficient d33 (1209 pC/N), and relatively low acoustic impedance Z (1.82 × 107 kg/(m2·s)). Besides, two types of Time-of-Flight Diffraction (TOFD) ultrasonic transducers have been designed, fabricated, and characterized, which have different matching layer schemes with the acoustic impedance of 4.8 and 5.7 × 106 kg/(m2·s), respectively. In the detection on a backwall of 12.7 mm polystyrene, the former exhibits higher detectivity, the relative pulse-echo sensitivity and -6 dB relative bandwidth are -21.93 dB and 102.7%, respectively, while the later exhibits broader bandwidth, the relative pulse-echo sensitivity and -6 dB relative bandwidth are -24.08 dB and 117.3%, respectively. These TOFD ultrasonic transducers based on PMNT/epoxy 1-3 composite exhibit considerably improved performance over the commercial PZT/epoxy 1-3 composite TOFD ultrasonic transducer.